The systematic and comprehensive geochemical analysis of fluoride (F) in twenty agricultural soil samples was carried out to understand spatial variability, mechanism of retention and release, and the areas of potential risk due to high concentrations of F in soil around Sidhi District, Central India. The spatial variations in physico-chemical parameters revealed significant difference in the methods of cultivation due to geomorphological constraints, availability of surface water and ground water etc., in the study area. The north and small pocket in central Sidhi were rich in fertile soils due to availability of surface and ground water. The southern and eastern Sidhi were rainfed areas, hence, the monocropping system by traditional methods showed less impact on the soil physico-chemical parameters. The soil F varied from 366.94 to 1178 mg/kg and 2-4 times greater than the background soil value (320 mg/kg) of the world. The pollution indexes were > 1 indicating prevalence of elevated soil fluorine.